Research Areas - (50) Chemistry

Full path: Chemistry

Department(s)/lab(s): Imaging Physics (ImPhys) | Adam Lab (THz near-field) @ TU Delft
Summary:

Aurèle Adam develops THz near-field imaging and spectroscopy. Research: (1) apertureless scattering-type near-field optical microscopy (s-SNOM) at THz frequencies for nanometre spatial resolution imaging of material properties; (2) THz time-domain spectroscopy of quantum materials and condensed matter systems; (3) antenna-coupled detectors and sources for THz near-field imaging. Relevant to quantum material characterisation at the nanoscale.

Department(s)/lab(s): Chemistry | PPSM - Luminescent Molecular Materials (Allain) @ ENSPS
Summary:

Allain (PPSM) designs luminescent and mechanofluorochromic molecular materials and lanthanide/organic probes acting as optical stress and environment sensors, including solid-state and time-resolved luminescence readouts. In the broader landscape of NV-centre ensemble quantum sensing (DEER, nano-NMR, T1 relaxometry) operating near pT/sqrt(Hz) sensitivity, this work is complemented by stimuli-responsive molecular luminescent sensors.

Department(s)/lab(s): Chemistry | Anderson Lab @ UChicago
Summary:

Anderson's group designs molecular electron-spin qubit candidates -- including an air- and water-stable tetrathiafulvalene-bridged radical with spin centered on a nuclear-spin-free ligand -- that retain hundreds of nanoseconds of coherence in solution at room temperature, aiming toward solution-phase quantum sensing in biological environments. This complements solid-state NV-ensemble sensors, which use DEER, NMR, and T1-relaxometry protocols to reach pT/sqrt(Hz)-class magnetic sensitivity, by pursuing a chemically tunable molecular alternative that could operate directly in biological media.

Department(s)/lab(s): Electrical & Electronic Engineering – Photon Science Institute | Boland Group (THz Semiconductor and 2D Materials Spectroscopy) @ Manchester
Summary:

Boland's group focuses on THz spectroscopy of semiconductor nanostructures and 2D materials for quantum sensing applications. Research directions: (1) THz optical pump–THz probe spectroscopy β€” measuring ultrafast carrier dynamics in semiconductor nanowires, quantum wells, and 2D materials (graphene, TMDs, perovskites) after optical excitation; (2) Near-field THz nanoscopy β€” sub-wavelength THz imaging of carrier distributions and quantum phase domains; (3) THz-active quantum devices β€” studying exciton and polaron dynamics in perovskite and III-V semiconductors at THz frequencies; (4) 2D material sensors β€” graphene-based THz detectors and emitters. Applications in quantum-material characterization and quantum sensing.

Department(s)/lab(s): School of Chemistry | Boskovic Molecular Magnetism Group @ UMelb
Summary:

Boskovic is a synthetic inorganic chemist working on lanthanoid and polyoxometalate molecular magnets, valence tautomeric and redox-switchable complexes, and the design of molecules whose spin states can be addressed and switched. The group's relevance to quantum sensing is that these are chemically tunable spin qubits: unlike solid-state defects, their coordination environment, nuclear-spin bath and anisotropy can be designed atom by atom, which is the argument for molecular qubits as sensors. Characterisation is by SQUID magnetometry, EPR and ab initio calculation. Positioned against the established body of NV-ensemble quantum sensing work β€” DEER, nanoscale NMR and T1 relaxometry protocols operating at pT/sqrt(Hz) field sensitivity β€” molecular spin qubits are the chemistry community's answer to the NV centre, and DEER/pulsed-EPR protocols developed for NV ensembles at pT/sqrt(Hz) transfer more or less directly to these systems. Borderline inclusion (synthesis-led rather than sensitivity-led), kept per the inclusive rubric.

Department(s)/lab(s): Chemistry | Boxer Lab @ Stanford
Summary:

Boxer's group uses vibrational Stark effect spectroscopy -- measuring field-dependent shifts of nitrile, carbonyl, and other IR-active vibrational probes -- to quantify electrostatic fields inside proteins, membranes, and active sites, providing a molecular-scale, spectroscopic route to electric-field sensing distinct from device-based quantum sensors. [Borderline match: a molecular spectroscopic probe of local fields rather than a fabricated quantum sensor; kept for review.]

Department(s)/lab(s): Biomedical Engineering (Physics affiliate) | Campagnola Lab @ UWMadison
Summary:

Develops second- and third-harmonic generation (SHG/THG) nonlinear optical microscopy to image collagen and other non-centrosymmetric structural proteins label-free in tissue, with applications to cancer diagnosis and fibrosis, pushing spatial/orientational resolution of structural imaging in intact tissue.

Department(s)/lab(s): School of Physics | Curmi Molecular Biophysics Laboratory @ UNSW
Summary:

Curmi is a structural and single-molecule biophysicist whose most-cited work is on the light-harvesting antenna proteins of cryptophyte algae, where he and collaborators reported long-lived electronic coherence at ambient temperature β€” one of the founding results of the quantum-biology field and still one of its most argued-over. His group determines the structures of these antenna complexes and engineers them, and separately works on protein-based molecular motors and on single-molecule fluorescence and FRET measurements of conformational dynamics. Positioned against the established body of NV-ensemble quantum sensing work β€” DEER, nanoscale NMR and T1 relaxometry protocols operating at pT/sqrt(Hz) field sensitivity β€” Curmi supplies the biological systems in which quantum coherence is actually claimed to matter; a pT/sqrt(Hz)-class spin sensor capable of watching radical-pair or exciton dynamics in situ would be aimed at exactly the questions his structures raise. Preferred attribute present: genuine quantum-biology substrate rather than a quantum-flavoured metaphor.

Department(s)/lab(s): Chemistry / PME | Engel Group @ UChicago
Summary:

Research focuses on quantum dynamics and excited-state reactivity in biological and synthetic light-harvesting systems. Discovered long-lived quantum coherence in photosynthetic light-harvesting complexes (FMO, 2007). Develops 2D electronic spectroscopy techniques to probe excitonic transport, open quantum systems, and photochemical reaction dynamics on femtosecond timescales. Director NSF QuBBE; co-director Berggren Center for Quantum Biology and Medicine.

Department(s)/lab(s): Chemistry | Fayer Group @ Stanford
Summary:

Fayer's group develops and applies ultrafast 2D infrared spectroscopy to resolve structural dynamics of water, proteins, and complex fluids on femtosecond-to-picosecond timescales, pushing the temporal resolution of vibrational spectroscopy well past what linear methods can access.