Basche is one of the founding figures of optical single-molecule spectroscopy. The group performs high-resolution fluorescence-excitation spectroscopy on single dibenzoterrylene (DBT) molecules in anthracene hosts at liquid-helium temperature, where zero-phonon lines approach the Fourier limit -- effectively a solid-state single-photon emitter with atom-like linewidths -- and studies how nanocrystal host engineering (e.g. electrohydrodynamic printing) preserves spectral stability, with polarization-resolved super-resolution imaging used to pin down crystal orientation. Further lines: photon-statistics and blinking in single quantum dots and QD/dye hybrids, and single-molecule studies of singlet fission, where photon-stream analysis of terrylenediimide dimers exposed coherent multiexciton superpositions that ensemble measurements average away. Relative to the established NV-ensemble quantum-sensing playbook (DEER, nanoscale NMR, T1 relaxometry at pT/sqrt(Hz) ensemble sensitivity), this is the molecular analogue of the colour-centre programme -- same photophysics toolkit (HBT, resonance fluorescence, orientation-resolved imaging), different emitter -- and it is the strongest single-emitter optics group in Mainz chemistry. Note: senior/long-established professor; confirm current group status and recruiting before applying.
McCamey is, for a candidate coming from NV ensemble sensing, the single most methodologically adjacent PI at UNSW. His laboratory does optically and electrically detected magnetic resonance on spins that are not defects in diamond: photogenerated spin-correlated radical pairs, triplet excitons in organic semiconductors, singlet-fission intermediates, and molecular spin systems. The instrumentation is the same toolkit — pulsed EPR, ODMR, dynamical decoupling, relaxometry — applied to systems where the spin is created by light and reports on chemistry. He directs the UNSW node of ARC Exciton Science. Positioned against the established body of NV-ensemble quantum sensing work — DEER, nanoscale NMR and T1 relaxometry protocols operating at pT/sqrt(Hz) field sensitivity — his group runs precisely those pulse sequences (Hahn echo, DEER, relaxometry) on a different spin species, and radical-pair spin chemistry is one of the few plausible mechanisms by which biology could be genuinely quantum — which makes this a strong landing spot for someone wanting to keep the NV skill set but change the physical system. Preferred attributes present: sensitivity-limited spin measurement, quantum-biology relevance.
Rao's group uses ultrafast (sub-20 fs) transient absorption and vibronic spectroscopy to study quantum-coherent energy and charge transfer processes in molecular and nanoscale semiconductor systems, most notably the quantum-coherent mechanism of singlet exciton fission, with applications to next-generation photovoltaics.